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Назив: Synthesis, structural, DFT, and cytotoxicity studies of Cu<sup>II</sup> and Ni<sup>II</sup> complexes with 3-aminopyrazole derivatives
Аутори: Barta Holló, Berta
Leovac V.
Bombicz P.
Kovacs A.
Jovanoviá L.
Bogdanovié G.
Kojić, Vesna
Divjaković V.
Joksović, Milan
Mészáros Szécsényi, Katalin
Датум издавања: 2010
Сажетак: Template synthesis of N,N′-bis(4-acetyl-5-methylpyrazole-3-yl) formamidine (ampf) was performed starting from 4-acetyl-3-amino-5-methylpyrazole (aamp) and CH(OC2H5)3 in methanol in the presence of CuCl2, Cu(NO3)2, or Ni(NO 3)2. The ligand was isolated in coordinated form as [Cu(ampf)Cl2], [Cu(ampf)(MeOH)(NO3)2]MeOH, and [Ni(ampf)(MeOH)2(NO3)]NO3 correspondingly. The compounds were characterized by elemental analysis, Fourier-transform IR and electronic spectroscopy, thermal analysis, single-crystal X-ray diffraction, and quantum chemical (density functional theory) calculations. The density functional theory calculations provided information on the metalligand interactions in the complexes and assisted the assignment of the FT-IR spectra. The antiproliferative activity of the complexes and the ligand precursor, aamp, was tested against human myelogenous leukaemia K562, colon adenocarcinoma HT29, and cervix carcinoma HeLa. © 2010 CSIRO.
URI: https://scidar.kg.ac.rs/handle/123456789/9710
Тип: article
DOI: 10.1071/CH10210
ISSN: 0004-9425
SCOPUS: 2-s2.0-78649756700
Налази се у колекцијама:Faculty of Science, Kragujevac

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