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Title: | Palladium(II) complexes with R<inf>2</inf>edda-derived ligands. Part V. Reaction of O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-(3-methyl) butanoate with K<inf>2</inf>[PdCl<inf>4</inf>] |
Authors: | Radic G. Jevtić, Verica Kaluđerović, Goran Heinemann F. Trifunović, Srećko |
Issue Date: | 2011 |
Abstract: | The reaction of K2[PdCl4] with [(S,S)-H 2(Et)2eddv]Cl2 diester (O,O′-diethyl-(S, S)-ethylenediamine-N,N′-di-2-(3-methyl)butanoate) (1) resulted in [PdCl2{(S,S)-(Et)eddv-κ2 N,N′,κO}] (2) complex with one hydrolyzed ester group. The compound was characterized by spectroscopic methods and it was found that the reaction is diastereoselective (1H and 13C NMR; one diastereoisomer of four possible). In addition, the structure of 2 was confirmed by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N′-configured isomer. DFT calculations support the formation of one diastereoisomer of 2. © 2011 Springer Science+Business Media B.V. |
URI: | https://scidar.kg.ac.rs/handle/123456789/10030 |
Type: | article |
DOI: | 10.1007/s11243-011-9473-3 |
ISSN: | 0340-4285 |
SCOPUS: | 2-s2.0-79955814606 |
Appears in Collections: | Faculty of Science, Kragujevac |
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