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Поље DC-а | Вредност | Језик |
---|---|---|
dc.rights.license | restrictedAccess | - |
dc.contributor.author | Radenkovic, Slavko | - |
dc.contributor.author | Shaik S. | - |
dc.contributor.author | Braida B. | - |
dc.date.accessioned | 2021-09-24T23:15:30Z | - |
dc.date.available | 2021-09-24T23:15:30Z | - |
dc.date.issued | 2021 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://scidar.kg.ac.rs/handle/123456789/13677 | - |
dc.description.abstract | Bonding in the recently synthesized NaBH3− cluster is investigated using the high level Valence Bond BOVB method. Contrary to earlier conclusions, the Na−B bond is found to be neither a genuine dative bond, nor a standard polar-covalent bond at equilibrium. It is rather revealed as a split and polarized weakly coupled electron-pair, which allows this cluster to be more effectively stabilized by a combination of (major) dipole-dipole electrostatic interaction and (secondary) resonant one-electron bonding mechanism. Our analysis of this unprecedented bonding situation extends to similar clusters, and the VB model unifies and articulates the previously published variegated views on this exotic “bond”. | - |
dc.rights | info:eu-repo/semantics/restrictedAccess | - |
dc.source | Angewandte Chemie - International Edition | - |
dc.title | Na⋅⋅⋅B Bond in NaBH<inf>3</inf><sup>−</sup>: Solving the Conundrum | - |
dc.type | article | - |
dc.identifier.doi | 10.1002/anie.202100616 | - |
dc.identifier.scopus | 2-s2.0-85105232504 | - |
Налази се у колекцијама: | Faculty of Science, Kragujevac |
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PaperMissing.pdf Ограничен приступ | 29.86 kB | Adobe PDF | ![]() Погледајте |
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