Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/13970
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dc.rights.licenseBY-NC-ND-
dc.contributor.authorStevanović, Dragana-
dc.contributor.authorBugarinović, Jovana-
dc.contributor.authorPešić, Marko-
dc.contributor.authorTodosijević A.-
dc.contributor.authorBogdanovic, Goran A.-
dc.contributor.authorDamljanović, Ivan-
dc.date.accessioned2022-02-02T17:41:39Z-
dc.date.available2022-02-02T17:41:39Z-
dc.date.issued2021-
dc.identifier.urihttps://scidar.kg.ac.rs/handle/123456789/13970-
dc.description.abstractA simple protocol has been developed for the chemoselective synthesis of ferrocene-containing Rauhut-Currier adducts from 1-ferrocenyl-2-nitroethene and vinyl ketones using 20 mol% of triphenylphosphine. Multifunctional ferrocene derivatives were obtained in moderate to high yields (51-92%) by the coupling between the α-position of vinyl ketones and the β-position of the nitroalkene. The study of the Rauhut-Currier reaction under the described conditions showed that the strong electron-donating group at the β-position of nitroalkenes plays a significant role in the reaction outcome due to prevention of polymerization and stabilization of the zwitterionic intermediate. Additionally, a preparative synthesis of 4-ferrocenyl-3-methylene-5-nitropentan-2-one was carried out and its synthetic transformations showed easy conversion to other useful building blocks. This journal is-
dc.rightsopenAccess-
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/-
dc.sourceRSC Advances-
dc.titleChemoselective synthesis of multifunctional ferrocene-containing derivatives by the cross Rauhut-Currier reaction-
dc.typearticle-
dc.identifier.doi10.1039/d1ra07619a-
dc.identifier.scopus2-s2.0-85120520260-
Appears in Collections:Faculty of Science, Kragujevac

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