Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/9710
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dc.rights.licenseBY-NC-ND-
dc.contributor.authorBarta Holló, Berta-
dc.contributor.authorLeovac V.-
dc.contributor.authorBombicz P.-
dc.contributor.authorKovacs A.-
dc.contributor.authorJovanoviá L.-
dc.contributor.authorBogdanovié G.-
dc.contributor.authorKojić, Vesna-
dc.contributor.authorDivjaković V.-
dc.contributor.authorJoksović, Milan-
dc.contributor.authorMészáros Szécsényi, Katalin-
dc.date.accessioned2020-09-19T18:56:24Z-
dc.date.available2020-09-19T18:56:24Z-
dc.date.issued2010-
dc.identifier.issn0004-9425-
dc.identifier.urihttps://scidar.kg.ac.rs/handle/123456789/9710-
dc.description.abstractTemplate synthesis of N,N′-bis(4-acetyl-5-methylpyrazole-3-yl) formamidine (ampf) was performed starting from 4-acetyl-3-amino-5-methylpyrazole (aamp) and CH(OC2H5)3 in methanol in the presence of CuCl2, Cu(NO3)2, or Ni(NO 3)2. The ligand was isolated in coordinated form as [Cu(ampf)Cl2], [Cu(ampf)(MeOH)(NO3)2]MeOH, and [Ni(ampf)(MeOH)2(NO3)]NO3 correspondingly. The compounds were characterized by elemental analysis, Fourier-transform IR and electronic spectroscopy, thermal analysis, single-crystal X-ray diffraction, and quantum chemical (density functional theory) calculations. The density functional theory calculations provided information on the metalligand interactions in the complexes and assisted the assignment of the FT-IR spectra. The antiproliferative activity of the complexes and the ligand precursor, aamp, was tested against human myelogenous leukaemia K562, colon adenocarcinoma HT29, and cervix carcinoma HeLa. © 2010 CSIRO.-
dc.rightsopenAccess-
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/-
dc.sourceAustralian Journal of Chemistry-
dc.titleSynthesis, structural, DFT, and cytotoxicity studies of Cu<sup>II</sup> and Ni<sup>II</sup> complexes with 3-aminopyrazole derivatives-
dc.typearticle-
dc.identifier.doi10.1071/CH10210-
dc.identifier.scopus2-s2.0-78649756700-
Appears in Collections:Faculty of Science, Kragujevac

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