Please use this identifier to cite or link to this item:
https://scidar.kg.ac.rs/handle/123456789/10030
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.rights.license | restrictedAccess | - |
dc.contributor.author | Radic G. | - |
dc.contributor.author | Jevtić, Verica | - |
dc.contributor.author | Kaluđerović, Goran | - |
dc.contributor.author | Heinemann F. | - |
dc.contributor.author | Trifunović, Srećko | - |
dc.date.accessioned | 2021-04-20T14:41:25Z | - |
dc.date.available | 2021-04-20T14:41:25Z | - |
dc.date.issued | 2011 | - |
dc.identifier.issn | 0340-4285 | - |
dc.identifier.uri | https://scidar.kg.ac.rs/handle/123456789/10030 | - |
dc.description.abstract | The reaction of K2[PdCl4] with [(S,S)-H 2(Et)2eddv]Cl2 diester (O,O′-diethyl-(S, S)-ethylenediamine-N,N′-di-2-(3-methyl)butanoate) (1) resulted in [PdCl2{(S,S)-(Et)eddv-κ2 N,N′,κO}] (2) complex with one hydrolyzed ester group. The compound was characterized by spectroscopic methods and it was found that the reaction is diastereoselective (1H and 13C NMR; one diastereoisomer of four possible). In addition, the structure of 2 was confirmed by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N′-configured isomer. DFT calculations support the formation of one diastereoisomer of 2. © 2011 Springer Science+Business Media B.V. | - |
dc.rights | info:eu-repo/semantics/restrictedAccess | - |
dc.source | Transition Metal Chemistry | - |
dc.title | Palladium(II) complexes with R<inf>2</inf>edda-derived ligands. Part V. Reaction of O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-(3-methyl) butanoate with K<inf>2</inf>[PdCl<inf>4</inf>] | - |
dc.type | article | - |
dc.identifier.doi | 10.1007/s11243-011-9473-3 | - |
dc.identifier.scopus | 2-s2.0-79955814606 | - |
Appears in Collections: | Faculty of Science, Kragujevac |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
PaperMissing.pdf Restricted Access | 29.86 kB | Adobe PDF | View/Open |
Items in SCIDAR are protected by copyright, with all rights reserved, unless otherwise indicated.