Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/10030
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dc.rights.licenserestrictedAccess-
dc.contributor.authorRadic G.-
dc.contributor.authorJevtić, Verica-
dc.contributor.authorKaluđerović, Goran-
dc.contributor.authorHeinemann F.-
dc.contributor.authorTrifunović, Srećko-
dc.date.accessioned2021-04-20T14:41:25Z-
dc.date.available2021-04-20T14:41:25Z-
dc.date.issued2011-
dc.identifier.issn0340-4285-
dc.identifier.urihttps://scidar.kg.ac.rs/handle/123456789/10030-
dc.description.abstractThe reaction of K2[PdCl4] with [(S,S)-H 2(Et)2eddv]Cl2 diester (O,O′-diethyl-(S, S)-ethylenediamine-N,N′-di-2-(3-methyl)butanoate) (1) resulted in [PdCl2{(S,S)-(Et)eddv-κ2 N,N′,κO}] (2) complex with one hydrolyzed ester group. The compound was characterized by spectroscopic methods and it was found that the reaction is diastereoselective (1H and 13C NMR; one diastereoisomer of four possible). In addition, the structure of 2 was confirmed by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N′-configured isomer. DFT calculations support the formation of one diastereoisomer of 2. © 2011 Springer Science+Business Media B.V.-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.sourceTransition Metal Chemistry-
dc.titlePalladium(II) complexes with R<inf>2</inf>edda-derived ligands. Part V. Reaction of O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-(3-methyl) butanoate with K<inf>2</inf>[PdCl<inf>4</inf>]-
dc.typearticle-
dc.identifier.doi10.1007/s11243-011-9473-3-
dc.identifier.scopus2-s2.0-79955814606-
Appears in Collections:Faculty of Science, Kragujevac

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