Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/10469
Title: Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition
Authors: Stevanović, Dragana
Pejović, Anka
Damljanović, Ivan
VukiĆ ević M.
Bogdanovic, Goran A.
Vukić ević R.
Issue Date: 2012
Abstract: An efficient catalyst for Ferrier rearrangement and hetero-Michael addition was successfully generated from a sacrificial zirconium anode into media containing reactants for these reactions. Thus, the catalyst generated, successfully promoted the allylic rearrangement of peracetylated D-glucal in the presence of a suitable S-nucleophile, giving the corresponding 2,3-unsaturated D-glucopyranose (pseudoglycal) in good to high yields. This catalyst was also shown to be capable of promoting hetero-Michael conjugate addition of S- and N-nucleophiles to the carbon-carbon double bond of methyl vinyl ketone, resulting in new carbon-sulfur and carbon-nitrogen bond formation. © 2012 Elsevier Ltd. All rights reserved.
URI: https://scidar.kg.ac.rs/handle/123456789/10469
Type: article
DOI: 10.1016/j.tetlet.2012.09.023
ISSN: 0040-4039
SCOPUS: 2-s2.0-84938482913
Appears in Collections:Faculty of Science, Kragujevac

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