Please use this identifier to cite or link to this item:
|Title:||Mechanistic insight into the formation of cinnamates in phosphine-free Heck reactions|
|Journal:||Monatshefte fur Chemie|
|Abstract:||A mechanistic study of the formation of cinnamates in phosphine-free Heck reactions was performed. Pathways for migratory insertion, β-hydride elimination, and catalyst recovery were elucidated using density functional theory (DFT) methods. It was shown that catalyst recovery is the rate-determining step of the overall Heck catalytic cycle. © Springer-Verlag 2012.|
|Appears in Collections:||Faculty of Science, Kragujevac|
Files in This Item:
|29.86 kB||Adobe PDF|
Items in SCIDAR are protected by copyright, with all rights reserved, unless otherwise indicated.