Please use this identifier to cite or link to this item:
https://scidar.kg.ac.rs/handle/123456789/10475
Title: | Mechanistic insight into the formation of cinnamates in phosphine-free Heck reactions |
Authors: | Petrović, Vladimir Markovic, Svetlana Petrović, Zorica |
Issue Date: | 2012 |
Abstract: | A mechanistic study of the formation of cinnamates in phosphine-free Heck reactions was performed. Pathways for migratory insertion, β-hydride elimination, and catalyst recovery were elucidated using density functional theory (DFT) methods. It was shown that catalyst recovery is the rate-determining step of the overall Heck catalytic cycle. © Springer-Verlag 2012. |
URI: | https://scidar.kg.ac.rs/handle/123456789/10475 |
Type: | article |
DOI: | 10.1007/s00706-012-0808-3 |
ISSN: | 0026-9247 |
SCOPUS: | 2-s2.0-84870362123 |
Appears in Collections: | Faculty of Science, Kragujevac |
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PaperMissing.pdf Restricted Access | 29.86 kB | Adobe PDF | View/Open |
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