Молимо вас користите овај идентификатор за цитирање или овај линк до ове ставке: https://scidar.kg.ac.rs/handle/123456789/10595
Пун извештај метаподатака
Поље DC-а ВредностЈезик
dc.rights.licenserestrictedAccess-
dc.contributor.authorPetrović, Zorica-
dc.contributor.authorPetrović, Vladimir-
dc.contributor.authorSimijonović, Dušica-
dc.contributor.authorMarkovic, Svetlana-
dc.date.accessioned2021-04-20T16:09:29Z-
dc.date.available2021-04-20T16:09:29Z-
dc.date.issued2012-
dc.identifier.issn1381-1169-
dc.identifier.urihttps://scidar.kg.ac.rs/handle/123456789/10595-
dc.description.abstractCatalytic systems trans-[PdCl 2(DEA) 2]/DEA and trans-[PdCl 2(DEA) 2]/[DEA][HAc], used in the model reaction of methyl methacrylate with iodobenzene, 4-iodoanisole, and bromobenzene, provide homogeneous catalysis, good regioselectivity and excellent stereoselectivity. The major product of the regioselective reaction is internal olefin. In all examined cases the only stereoisomer of the internal olefin methyl 3-phenyl-2-methylpropenoate is the E-isomer, whereas the only stereoisomer of the double arylated reaction product methyl 2-benzyl-3- phenylpropenoate is the Z-isomer. A DFT study, which investigates mechanistic aspects of migratory insertion, β-hydride elimination and reductive elimination of this phosphine-free Heck reaction, is in agreement with our experimental findings. © 2012 Elsevier B.V. All rights reserved.-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.sourceJournal of Molecular Catalysis A: Chemical-
dc.titleStereoselective homogeneous catalytic arylation of methyl methacrylate: Experimental and computational study-
dc.typearticle-
dc.identifier.doi10.1016/j.molcata.2012.01.007-
dc.identifier.scopus2-s2.0-84857360039-
Налази се у колекцијама:Faculty of Science, Kragujevac
Institute for Information Technologies, Kragujevac

Број прегледа

1748

Број преузимања

22

Датотеке у овој ставци:
Датотека Опис ВеличинаФормат 
PaperMissing.pdf
  Ограничен приступ
29.86 kBAdobe PDFСличица
Погледајте


Ставке на SCIDAR-у су заштићене ауторским правима, са свим правима задржаним, осим ако није другачије назначено.