Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/12457
Title: The palladium(ii) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: Synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction
Authors: Damljanović, Ivan
Stevanović, Dragana
Pejović, Anka
Ilić Komatina D.
Zivkovic, Marija
Bugarinović, Jovana
Vukićević, Miomir
Bogdanovic, Goran A.
Radulovic, Niko
Vukicevic R.
Issue Date: 2014
Abstract: © the Partner Organisations 2014. In this paper we wish to present the first results on the synthesis of N,N-diethyl-1-ferrocenyl-3-thiabutanamine, its coordination with palladium(ii), the complete characterization of the thus obtained complex (including single crystal X-ray analysis for the complex in two polymorphic forms) and screening of its catalytic activity in Suzuki-Miyaura coupling of phenylboronic acid with several aryl bromides. The complex, either purified and then added to the reaction mixture or generated in situ, proved to be an excellent precatalyst in Suzuki-Miyaura coupling. The chemical behavior of the complex in solution was assessed by detailed NMR analyses and cyclic voltammetry measurements which allowed us to draw a number of mechanistic conclusions. This journal is
URI: https://scidar.kg.ac.rs/handle/123456789/12457
Type: article
DOI: 10.1039/c4ra08140d
SCOPUS: 2-s2.0-84907833845
Appears in Collections:Faculty of Medical Sciences, Kragujevac
Faculty of Science, Kragujevac

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