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Title: Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide
Authors: Pejović, Anka
Damljanović, Ivan
Stevanović, Dragana
Ilić Komatina D.
Vukićević, Miomir
Bogdanovic, Goran A.
Vukicevic R.
Journal: Tetrahedron Letters
Issue Date: 28-Aug-2013
Abstract: Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferrocenyl-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding β-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. © 2013 Elsevier Ltd. All rights reserved.
Type: article
DOI: 10.1016/j.tetlet.2013.06.130
ISSN: 00404039
SCOPUS: 84880839901
Appears in Collections:Faculty of Science, Kragujevac

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