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|Title:||Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide|
|Authors:||Pejović, Anka |
Ilić Komatina D.
Bogdanovic, Goran A.
|Abstract:||Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferrocenyl-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding β-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. © 2013 Elsevier Ltd. All rights reserved.|
|Appears in Collections:||Faculty of Science, Kragujevac|
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