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DC Field | Value | Language |
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dc.contributor.author | El Doukkali, M. | - |
dc.contributor.author | Iriondo, A. | - |
dc.contributor.author | Miletic, Nemanja | - |
dc.contributor.author | Cambra, J.F. | - |
dc.contributor.author | Arias, P.L. | - |
dc.date.accessioned | 2024-01-11T12:29:38Z | - |
dc.date.available | 2024-01-11T12:29:38Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | El Doukkali, M., Iriondo, A., Miletic, N., Cambra, J.F., Arias, P.L. (2017): Hydrothermal stability improvement of NiPt-containing γ-Al2O3 catalysts tested in aqueous phase reforming of glycerol/water mixture for H2 production. International Journal of Hydrogen Energy, 42(37), 23617-23630 | en_US |
dc.identifier.issn | 03603199 | en_US |
dc.identifier.uri | https://scidar.kg.ac.rs/handle/123456789/19845 | - |
dc.description.abstract | The hydrothermal stability of Ni and NiPt-containing g-Al2O3 catalysts in aqueous phase reforming (APR) of glycerol/water mixture (C3H8O3/H2O, 10% w/w) was investigated putting in evidence the influence of the preparation method; sol-gel in basic medium (SGB) and impregnation on an in-house prepared sol-gel g-Al2O3 support (SGI). All developed catalysts were characterized by ICP-AES, TPR-H2, in-situ heating XRD-O2, DSC/TG-N2/O2 and ex-situ reduction of XRD-H2, N2 physisoption and TEM techniques. The results indicate that SGI method and calcination treatment at 750 C were crucial in extending the catalytic useful life of NiPt-containing g-Al2O3 catalysts, resulting in an adequate distribution of Ni-Pt metallic particles and good stability of g-Al2O3 support against the severe hydrothermal conditions of APR process. The SGI method led to form stable NiPt catalysts with relatively big Ni particles and stable hydrothermal properties of g-Al2O3 support, while the SGB catalysts exhibited well-dispersed Ni particles but unstable catalytic behavior. These last catalysts presented high glycerol conversions during the first hours of APR glycerol/water reaction, however, an important decrease in terms of glycerol conversion was observed after 24 h time-on-stream. The experimental results suggested that the most suitable stable and active catalyst was the NiPt/ASGI7 (better than >NiPt/ASGI6 > NiPt/ASGI5 >>> NiPt/ASGB7). This catalyst showed best catalytic activity and good catalytic stability along 56 h of time-on-stream, reaching, at steady state, highest total glycerol conversion (z79%) and glycerol into gaseous products (z57%) in APR reaction of glycerol/water mixture for hydrogen generation. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.relation.ispartof | International Journal of Hydrogen Energy | en_US |
dc.subject | NiPt-containing g-Al2O3 catalysts | en_US |
dc.subject | Impregnation/sol-gel methods | en_US |
dc.subject | Calcination treatment | en_US |
dc.subject | Hydrothermal stability improvement | en_US |
dc.subject | Glycerol aqueous phase reforming | en_US |
dc.title | Hydrothermal stability improvement of NiPt-containing γ-Al2O3 catalysts tested in aqueous phase reforming of glycerol/water mixture for H2 production | en_US |
dc.type | article | en_US |
dc.description.version | Published | en_US |
dc.identifier.doi | 10.1016/j.ijhydene.2017.04.218 | en_US |
dc.type.version | PublishedVersion | en_US |
dc.identifier.wos | 000412607800024 | en_US |
Appears in Collections: | Faculty of Agronomy, Čačak |
Files in This Item:
File | Description | Size | Format | |
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30 International Journal of Hydrogen Energy (2017).pdf Restricted Access | 2.45 MB | Adobe PDF | View/Open |
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