Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/8746
Title: Synthesis and Characterization of Zinc(II)-Complexes with S-Alkyl Derivatives of Thiosalicylic Acid
Authors: Nikolic, Milos
Mijajlovic M.
Tomović D.
Bukonjić A.
Jevtić, Verica
Ratković, Zoran
Trifunović, Srećko
Radic G.
Issue Date: 2017
Abstract: © 2017 IUPAC & De Gruyter. New zinc(II)-complexes with S-alkyl derivatives of thiosalicylic acid (alkyl = benzyl-(L1), methyl-(L2), ethyl-(L3), propyl-(L4), butyl-(L5)) have been synthesized and characterized by elemental microanalysis, IR spectroscopy, and 1H and 13C NMR spectroscopy. The S-alkyl derivatives of thiosalicylic acid were prepared by alkylation of thiosalicylic acid by adding alkyl halides to an alkaline water-ethanol solution, while the corresponding zinc(II)-complexes were obtained via the direct reaction of ZnCl2 with S-alkyl derivatives of thiosalicylic acid in water. Based on the microanalysis results and the IR and NMR spectra of the S-alkyl derivatives of thiosalicylic acid and the corresponding zinc(II)-complexes, we concluded that the ligands are bidentately coordinated to the zinc(II)-ion.
URI: https://scidar.kg.ac.rs/handle/123456789/8746
DOI: 10.1515/sjecr-2017-0005
ISSN: 1820-8665
SCOPUS: 2-s2.0-85038575798
Appears in Collections:Faculty of Medical Sciences, Kragujevac
Faculty of Science, Kragujevac

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