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Title: Synthesis and characterization of platinum(IV)-complexes with S-alkyl derivatives of thiosalicylic acid and the crystal structure of the S-butyl derivative of thiosalicylic acid
Authors: Mijajlovic M.
Nikolic, Milos
Tomović D.
Bukonjić A.
Kocovic, Aleksandar
Jevtić, Verica
Ratković, Zoran
Klisuric, Olivera
Trifunović, Srećko
Radic G.
Journal: Serbian Journal of Experimental and Clinical Research
Issue Date: 1-Sep-2017
Abstract: © 2017, University of Kragujevac, Faculty of Science. All rights reserved. New platinum(IV)-complexes with S-alkyl derivatives of thiosalicylic acid (alkyl = benzyl-(L1), methyl-(L2), ethyl-(L3), propyl-(L4), butyl-(L5)) have been synthesized and characterized by microanalysis, infrared spectroscopy, and1H and13C NMR spectroscopy. The bidentate S,O ligand precursor, the S-butyl derivative of thiosalicylic acid (S-bu-thiosal), was prepared, and its crystal structure was determined. Single crystals suitable for X-ray measurements were obtained by slow crystallization from a DMSO-water system. S-bu-thiosal crystallized in a P21/c space group of a monoclinic crystal system with a = 8.0732 (3) Å, b = 19.6769 (4) Å, c = 8.2291 (3) Å and Z = 4. S-bu-thiosal also has a coplanar geometry.
Type: Article
DOI: 10.1515/SJECR-2016-0094
ISSN: 18208665
SCOPUS: 85030715452
Appears in Collections:Faculty of Medical Sciences, Kragujevac
Faculty of Science, Kragujevac
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