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Title: 1-Ferrocenyl-3-(2-methylanilino)propan-1-one
Authors: Leka Z.
Novakovic, Sladjana B.
Pejović, Anka
Bogdanovic, Goran A.
Vukicevic R.
Journal: Acta Crystallographica Section E: Structure Reports Online
Issue Date: 1-Jul-2012
Abstract: In the ferrocene-containing Mannich base, [Fe(C5H 5)(C15H16NO)], the dihedral angle between the mean planes of the benzene ring and the substituted cyclopentadienyl ring is 84.63 (7)°. The conformation of the title compound significantly differs from those found in corresponding m-tolylamino and p-tolylamino derivatives. In the crystal, C - H⋯O interactions connect the molecules into chains, which further interact by means of C - H⋯π interactions. It is noteworthy that the amino H atom is shielded and is not involved in hydrogen bonding. © 2012 International Union of Crystallography.
Type: Article
DOI: 10.1107/S1600536812028802
SCOPUS: 84863594471
Appears in Collections:Faculty of Science, Kragujevac
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