Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/11793
Title: Stereo- and regioselective synthesis of cyclic ethers by means of organoseleniummediated cyclization of unsaturated alcohols
Authors: Bugarčić Z.
Kostic, Marina
Divac, Vera
Issue Date: 2016
Abstract: © 2016 Bentham Science Publishers. In the past several decades, significant progress has been made in the exploration of cyclofunctionalization reactions promoted by electrophilic organoselenium reagents. Numerous natural and biologically active products have been prepared by using this synthetic route. Increased research interest in this topic brings several relevant reviews, which cover wide scope of selenium-induced heterocyclizations. The reaction of electrophile selenium-induced cyclization of alkenes bearing suitable oriented hydroxyl group (termed selenoetherification) present useful tool for the preparation of different cyclic ethers units, which are the key structural units of many natural products. The coverage of this review will be limited to the examples of stereoselective and regioselective synthesis of five- and six-membered cyclic ethers by means of selenium-induced cyclization of unsaturated alcohols. The influence of some Lewis acids and bases, as additives, on regioselection of selenoetherification reaction will be also discussed.
URI: https://scidar.kg.ac.rs/handle/123456789/11793
Type: article
DOI: 10.2174/1385272819666150917011909
ISSN: 1385-2728
SCOPUS: 2-s2.0-84958962836
Appears in Collections:Faculty of Science, Kragujevac
Institute for Information Technologies, Kragujevac

Page views(s)

190

Downloads(s)

7

Files in This Item:
File Description SizeFormat 
PaperMissing.pdf
  Restricted Access
29.86 kBAdobe PDFThumbnail
View/Open


Items in SCIDAR are protected by copyright, with all rights reserved, unless otherwise indicated.