Please use this identifier to cite or link to this item: https://scidar.kg.ac.rs/handle/123456789/12183
Title: Experimental and theoretical study of antioxidative properties of some salicylaldehyde and vanillic Schiff bases
Authors: Petrović, Zorica
Orović J.
Simijonović, Dušica
Petrović, Vladimir
Marković, Zoran
Journal: RSC Advances
Issue Date: 1-Jan-2015
Abstract: © The Royal Society of Chemistry 2015. The antioxidative capacity and structure-activity relationships of ten Schiff bases were investigated experimentally and theoretically. All compounds contain the aniline moiety, while the aldehyde part is either salicylaldehyde or vanillin. The DPPH assay was used to test the potential antioxidative activity of these compounds, and DFT study was used to investigate their electronic structures and provide insight into their structure-activity relationships. The effect of the position of the hydroxy, as well other groups present, on the antioxidative activity was examined. The possible radical scavenging mechanism was determined in polar (water and methanol), and nonpolar (benzene) solvents. Based on the experimental and computational results, compounds 7 and 8 exhibit the highest radical scavenging properties.
URI: https://scidar.kg.ac.rs/handle/123456789/12183
Type: article
DOI: 10.1039/c5ra02134k
SCOPUS: 84924854875
Appears in Collections:Faculty of Science, Kragujevac
Institute for Information Technologies, Kragujevac

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